CDXBZ - 1,4-DIOXANE, DIII
- MSDS: CDXBZ
- Manufacturer: FISHER SCIENTIFIC
- Product Name: 1,4-DIOXANE, DIII
- National Stock Number: 6810-01-088-6266
Product Identification
Product ID:1,4-DIOXANE, DIII
MSDS Date:07/12/1990
FSC:6810
NIIN:01-088-6266
MSDS Number: CDXBZ
Responsible Party
FAIR LAWN, NJ 07410
US
Emergency Phone: 201-796-7100,800-424-9300(CHEMTREC)
Info Phone: 201-796-7100
Cage: 1B464
Contractor
Telephone: 201-796-7100
Cage: 1B464
Ingredients
1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA 313) (CERCLA)
CAS: 123-91-1
RTECS: JG8225000
Fraction By Weight: 100.0%
OSHA PEL S, 100 PPM
ACGIH TLV: S, 25 PPM; 9495
EPA Report Quantity: 100 LBS
DOT Report Quantity: 100 LBS
INHIBITORS
Fraction By Weight: 100.0%
OSHA PEL N/K
ACGIH TLV: N/K
SIGNS OF UNSTEADINESS, INCOORDINATION,
RTECS: 9999999ZZ
VAPS MAY CAUSE IRRIT AT CONCS ABOVE 220 PPM.
RTECS: 9999999ZZ
MAY CAUSE LIGHT BURNING SENSATION ON CNTCT
RTECS: 9999999ZZ
DEPRESS, COMA & DEATH IN ANIMALS. AUTOPSY REVEALED
RTECS: 9999999ZZ
BLADDERS DISTENDED W/URINE, SLIGHT PROTEINURIA &
RTECS: 9999999ZZ
RPTD EXPOS CAUSE MUC MEMB IRRIT, DYSPNEA, HDCH,
RTECS: 9999999ZZ
TENDERNESS IN THE ABDOMEN & LUMBAR REGION, DROW,
RTECS: 9999999ZZ
UREMIA, COMA, & DEATH FROM ACUTE RENAL FAILURE.
RTECS: 9999999ZZ
NECROSIS, HEMORRHAGIC NEPHRITIS & NECROSIS,
RTECS: 9999999ZZ
MAY CAUSE DRYING & CRACKING OF THE SKIN, DERM, &
RTECS: 9999999ZZ
DEATH OF A WORKER FOLLOWING SKIN & INHAL EXPOS FOR
RTECS: 9999999ZZ
MAY RSLT IN LIVER & KIDNEY DMG. TUMOR PROMOTER
RTECS: 9999999ZZ
IN ANIMAL FEEDING STUDIES, THIS
RTECS: 9999999ZZ
ULCERATION OF THE STOMACH, HEPATOMAS, CARCINOMA OF
RTECS: 9999999ZZ
LEUKEMIA, LYMPHOSARCOMA, CHOLANGIOMAS, GALL BLADDER
RTECS: 9999999ZZ
EFFECTS HAVE BEEN REPORTED IN ANIMALS.
RTECS: 9999999ZZ
NO SMOKING, FLAMES OR FLARES IN HAZARD AREA.
RTECS: 9999999ZZ
TO PREVENT REPEATED OR PROLONGED SKIN
RTECS: 9999999ZZ
AND FULL LENGTH FACESHIELD .
RTECS: 9999999ZZ
ARE EXPLOSIVE. DUE TO LOW ELECTROCONDUCTIVITY OF
RTECS: 9999999ZZ
ELECTROSTATIC CHARGES RESULTING IN SPARKS WITH
RTECS: 9999999ZZ
Hazards
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL: MAY BE IRRITATING TO
NOSE, THROAT & RESP TRACT AT 220 PPM. THIS CMPD HAS POOR WARNING
PROPERTIES & CAN BE INHALED IN AMTS THAT MAY CAUSE SERIOUS SYSTEMIC
INJURY. SYMPS OF SYSTEMIC TOX MAY INCL HDCH, VERTIGO, DROW,
DYSPNEA, NAUS, & VOMIT. INHAL CAUSED INCRD SALIVATION, LACRIMATION,
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:NARCOSIS, BEHAVIORAL CHANGES, & DEATH
IN ANIMALS. AUTOPSY REVEALED LUNG, LIVER & KIDNEY DMG, CONGESTION &
EDEMA OF THE LUNGS, & INCR BLOOD COUNTS. SKIN:MAY CAUSE IRRIT
W/REDNESS & PAIN. ALLER GIC CNTCT DERM HAS BEEN RPTD. SKIN
ABSORPTION MAY OCCUR & CAUSE HDCH, NAUS & VOMIT. SKIN ABSORPTION
PRDCED (ING 3)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
First Aid
First Aid:INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES: IMMEDIATELY FLUSH
W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM
MD . SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . FOR MORE
SPECIFIC INFORMATION CONTACT NEHC .
Fire Fighting
Flash Point Method:CC
Flash Point:54.0F,12.2C
Lower Limits:2.0%
Upper Limits:22%
Extinguishing Media:EXTING ONLY IF FLOW CAN BE STOPPED; USE H*2O IN
FLOODING AMTS AS FOG, SOLID STREAMS MAY NOT BE EFTIVE. COOLS
(SUPDAT)
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . FOR MORE SPECIFIC INFORMATION CONTACT NEHC .
Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZ WHEN EXPOSED TO
HEAT/FLAME. VAPS ARE HVR/AIR & MAY TRAVEL A CONSIDERABLE DISTANCE
TO A SOURCE OF IGNIT & FLASH BACK. VAPOR-AIR MIX (ING 22)
Accidental Release
Spill Release Procedures:SHUT OFF IGNIT SOURCES. STOP LEAK IF YOU CAN
DO IT W/OUT RISK. USE WATER SPRAY TO REDUCE VAPS. FOR SMALL SPILLS,
TAKE UP W/SAND/OTHER ABSORB MATL & PLACE INTO CNTNRS FOR LATER
DISP. FOR LRGR SPILLS, D IKE FAR AHEAD OF SPILL FOR LATER DISP.
(ING 19)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
Handling
Handling and Storage Precautions:STORE I/A/W 29 CFR 1010 108. STORE
AWAY FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:BONDING & GROUNDING: SUBSTANCES W/LOW
ELECTROCONDUCTIVITY, WHICH MAY BE IGNITED BY ELECTROSTATIC SPARKS,
SHOULD BE STORED IN CNTNR WHICH MEETS THE BONDING & GROUNDING
GUIDELINES SPECIFIED IN NFPA. FOR MORE SPECIFIC INFO CONTACT NEHC
.
Exposure Controls
Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . FOR MORE SPECIFIC INFORMATION CONTACT NEHC .
Ventilation:PROCESS ENCLOSURE VENTILATION RECOMMENDED TO MEET PUBLISHED
EXPOSURE LIMITS. VENTILATION EQUIP MUST BE EXPLOSION-PROOF.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(ING 21)
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
EMPLOYEE MUST WEAR APPROP PROT (IMPERVIOUS) CLTHG & EQUIP (ING 20)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MATLS TO AVOID:FOR MORE SPECIFIC INFO CNTCT NEHC . EXTING MEDIA:CNTNRS
W/FLOODING QTIES OF H*2O, APPLY FROM AS FAR A DISTANCE AS POSS
AVOID BRTHG TOX VAPS, KEEP UPWIND. CNDTNS (STAB):MAY VIOLENT LY
RUPTURE IN HEAT/FIRE. AVOID CONTAM OF WATER SOURCES.
Chemical Properties
Boiling Pt:B.P. Text:214F,101C
Melt/Freeze Pt:M.P/F.P Text:54.0F,12.2C
Vapor Pres:40 @ 25C
Vapor Density:3.0
Spec Gravity:1.0337
Evaporation Rate & Reference:2.7 (BUTYL ACETATE=1)
Solubility in Water:100%
Appearance and Odor:COLORLESS LIQUID WITH A FAINT, ETHEREAL ODOR.
Stability
Stability Indicator/Materials to Avoid:YES
DECABORANE, NICKEL (RANEY CATALYST), NITRIC ACID + PERCHLORIC ACID,
OXIDIZERS (STRONG), SILVER PERCHLORATE (SUPDAT)
Stability Condition to Avoid:AVOID CNTCT W/HEAT, SPARKS, FLAMES/OTHER
SOURCES OF IGNIT. VAPS MAY BE EXPLOSIVE & POISONOUS; DO NOT ALLOW
(SUPDAT)
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC OXIDES OF CARBON.
Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION HAS NOT
BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES.
Disposal
Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS
WHEN STORING OR DISPOSING OF THIS SUBSTANCE. DISPOSAL MUST BE IN
ACCORDANCE WITH STANDARD APPLICABLE TO GENERATORS OF HAZARDOUS
WASTE.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.